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<span>發布時間：2019/06/24</span> </div> <div class="bshare-custom view-share" ><a title="更多平臺" class="bshare-more bshare-more-icon more-style-addthis"></a><a title="分享到QQ空間" class="bshare-qzone"></a><a title="分享到新浪微博" class="bshare-sinaminiblog"></a><a title="分享到人人網" class="bshare-renren"></a><a title="分享到騰訊微博" class="bshare-qqmb"></a><a title="分享到網易微博" class="bshare-neteasemb"></a></div><script type="text/javascript" charset="utf-8" src="http://static.bshare.cn/b/buttonLite.js#style=-1&uuid=bcbe1edc-8ba3-4491-a1e6-19c8931d0292&pophcol=2&lang=zh"></script> <script type="text/javascript" charset="utf-8" src="http://static.bshare.cn/b/bshareC0.js"></script>  <br /> <div>　　聚氨酯涂料是較常見的一類涂料，可以分為雙組分聚氨酯涂料和單組分聚氨酯涂料。雙組分聚氨酯涂料一般是由異氰酸酯預聚物（也叫低分子氨基甲酸酯聚合物）和含羥基樹酯兩部分組成，通常稱為固化劑組分和主劑組分。</div> <div>　　根據含羥基組分的不同可分為：丙烯酸聚氨酯、醇酸聚氨酯、聚酯聚氨酯、聚醚聚氨酯、環氧聚氨酯等品種。</div> <div>　　按包裝類型分類，可分為單罐裝聚氨酯漆、雙罐裝聚氨酯漆、三罐裝聚氨酯漆。家庭裝飾通常選用三罐裝聚氨酯漆(即一罐主漆、一罐固化劑、一罐稀釋劑)。</div> <div>　　按其組成和成膜機理而將其分為五大類：聚氨酯改性油涂料、潮氣固化聚氨酯涂料、封閉型聚氨酯涂料、催化固化型聚氨酯涂料和羥基固化型聚氨酯涂料。</div> <div>　　雙組分聚氨酯涂料</div> <div>　　雙組分聚氨酯涂料具有成膜溫度低、附著力強、耐磨性好、硬度大以及耐化學品、耐候性好等優越性能，廣泛作為工業防護、木器家具和汽車涂料。水性雙組分聚氨酯涂料將雙組分溶劑型聚氨酯涂料的高性能和水性涂料的低VOC含量相結合，成為涂料工業的研究熱點。水性雙組分聚氨酯涂料是由含－OH基的水性多元醇和含－NCO基的低黏度多異氰酸酯固化劑組成，其涂膜性能主要由羥基樹脂的組成和結構決定。</div> <div>　　單組分水性聚氨酯涂料</div> <div>　　單組分水性聚氨酯涂料是以水性聚氨酯樹脂為基料，并以水為分散介質的一類涂料。通過交聯改性的水性聚氨酯涂料具有良好的儲存穩定性、涂膜力學性能、耐水性、耐溶劑性及耐老化性能，而且與傳統的溶劑型聚氨酯涂料的性能相近，是水性聚氨酯涂料的一個重要發展方向。</div> <div>　　光固化水性聚氨酯涂料</div> <div>　　光固化水性聚氨酯涂料采用電子束輻射、紫外光輻射的高強度輻射引發低活性的預聚物體系產生交聯固化，以紫外光固化形式為主。先用不飽和聚酯多元醇制備預聚物，然后用常規的方法引進粒子基因，經親水處理后制得在主鏈上帶雙鍵的聚氨酯水分散體，再與易溶的高活性三丙烯酸烷氧基酯單體、光敏劑等助劑混合得到光固化水性聚氨酯涂料。</div> <div>　　室溫固化水性聚氨酯涂料</div> <div>　　對于某些熱敏基材和大型制件，不能采用加熱的方式交聯，必須采用室溫交聯的水性聚氨酯涂料。通過與水分散性多異氰酸酯結合，可以改進水性端羥基聚氨酯預聚物/丙烯酸酯混合物，尤其是羥基丙烯酸酯混合物的性能。此類水性聚氨酯涂料，采用特制的多異氰酸酯交聯劑，即含－NCO端基的異氰酸酯預聚物，經親水處理后分散于各種含羥基聚合物中而形成分散體，與多種含羥基聚合物水分散體組成能在室溫固化的聚氨酯水性涂料。</div> <div>　　第三代水性聚氨酯涂料(PUA)</div> <div>　　聚氨酯（PU）乳液和聚丙烯酸（PA）乳液同其溶劑型產品相比，具有低廉，安全，不燃燒，無毒，不污染環境等優點。純PA乳液存在耐磨性、耐水性和耐化學品性差的缺陷，固含量高，應用范圍不廣等。PU和PA在性質上具有互補作用。PUA復合乳液兼備了二者的優點，具有耐磨、耐腐蝕和光亮，柔軟有彈性，耐水性和力學性能好，耐候性佳等特性，因此被譽為"第三代水性聚氨酯"，成為當今涂料一個發展趨勢。</div> <div>　　環保型低芳烴聚氨酯涂料</div> <div>　　該涂料既可彌補水性涂料性能不足，保持溶劑型涂料的優異性能。又可減少涂料對環境的影響。兼顧性能與環保性，較好地解決了這一問題。該涂料體系采用氣味小、毒性低的石油類低極性溶劑為稀釋劑?？娠@著減少對環境產生污染的物質，如苯、二甲苯及有害廢氣污染物(HAPs)的排放量，作為溶劑體系涂料，它還具有良好的涂膜及施工性能，在冬季低溫條件下也可施工。此外，由于該涂料體系中溶劑的溶解力低，不會產生侵蝕，因而易于重涂。并可用于噴涂易被溶劑侵蝕的材料。</div> <div>　　中國木器用高檔涂料主要有聚氨酯漆（PU）和聚酯漆（PE）兩大類。在國家標準分類中屬完全不同的兩大類涂料，即在類別、組成、性能、應用與固化機理等方面有很大區別。</div> <div>　　1.組成基料：聚酯漆（PE）類：不飽和聚酯，交聯單體；聚氨酯漆（PU）類：聚酯、丙烯酸樹酯、聚醚、環氧樹酯（含羥基-OH組分常稱主劑或乙組分）多異氰酸基的加成物或預聚物（含異氰酸基-NCO組分</div> <div>　　聚酯漆包圓銅線</div> <div>　　聚酯漆包圓銅線</div> <div>　　常稱硬化劑或甲組分）</div> <div>　　2.組分數聚酯漆（PE）類：3-4組分，3組分的是非蠟型聚酯漆，4組分的為蠟型聚酯漆。組分一，是不飽和聚酯的苯乙烯溶液（主劑）；組分二，是引發劑（又稱固化劑、硬化劑、俗名白水）；組分三，是促進劑（俗名蘭水）；組分四，是4%的石蠟苯乙烯溶液。聚氨酯漆（PU）類：1-3組分，有單組分、雙組分，后者調漆時還有稀釋劑，一般配漆比例為：主劑∶固化劑∶稀釋劑為1∶0.5-1∶0.5-1.5</div> <div>　　3.分類聚酯漆（PE）類：PE分氣干PE和嫌氧PE、嫌氧PE又分蠟型PE和非蠟型PE；聚氨酯漆（PU）類：PU分單組分和雙組分、單組分氨酯油和氨酯醇酸。PU的種類很多，市場主要是雙組分羥基固化型PU。</div> <div>　　4.溶劑聚酯漆（PE）類：苯乙烯等（即是溶劑、又是成膜物質）；聚氨酯漆（PU）類：無水二甲苯、無水環已酮或無水醋酸丁酯</div> <div>　　5.固體含量聚酯漆（PE）類：接近100%；聚氨酯漆（PU）類：40-70%</div> <div>　　6.施工時限（配漆使用期限、活性期）聚酯漆（PE）類：15-20min；聚氨酯漆（PU）類：4-8h</div> <div>　　7.固化條件與機理聚酯漆（PE）類：傳統嫌氧聚酯需隔氧固化（蠟封法）、新型氣干聚酯不必隔氧可固化，不飽和聚酯與苯乙烯在引發劑促進劑作用下發生游離基聚合反應交聯固化成膜。聚氨酯漆（PU）類：可常溫氣干或低溫（50℃）烘干。涂層中溶劑揮發，含異氰酸基組份與含羥基組份之間發生加成聚合反應固化成膜。</div> <div>　　8.施工衛生條件聚酯漆（PE）類：屬無溶劑型漆，漆中所含部分溶劑涂飾后與不飽聚酯發生共聚反應，共同成膜基本無有害氣體揮發。聚氨酯漆（PU）類：屬溶劑型漆，漆中含30-60%有機溶劑，涂飾后需全部揮發，污染環境，有毒有味，易燃易爆，需加強通風，有害物質（揮發性有機物、苯、甲苯、二甲苯TDI與重金屬）限量國家標準《室內裝飾裝修材料溶劑型涂料中有害物質限量》GB18581-2001已明確規定。</div> <div>　　9.干燥時間聚酯漆（PE）類：表干30-40min，打磨6-10h，實干>24h；聚氨酯漆（PU）類：表干15-20min，打磨3-4h，實干<24h</div> <div>　　10.重涂間隔聚酯漆（PE）類：可采用"濕碰濕"工藝即表干即涂；聚氨酯漆（PU）類：可采用"濕碰濕"工藝即表干即涂</div> <div>　　11.性能聚酯漆（PE）類：漆膜具優異綜合理化性能并具無溶劑型漆獨特特點；聚氨酯漆（PU）類：漆膜具優異綜合理化性</div> <div>　　市場上常見的所謂"聚酯漆"，實際上是聚氨酯漆。它是雙組分，一個是主漆，另一個是固化劑，使用時按要求的比例混合，再加適量的稀釋劑，攪拌均勻就可以涂刷了，工藝簡單，適合家庭裝修用。區分"聚酯漆"和"聚氨酯漆"。最簡單的辦法是："聚酯漆"配套的東西多，有四個組分。而"聚氨酯漆"配套的東西少，有單組分和雙組分兩大類，市場上雙組分的產品居多，即一個是主漆，一個是固化劑，配比和施工都相對的容易些。</div> <div>　　1.稀釋劑是以環已酮.醋酸丁酯.無水二甲苯所配制而成的混合有機溶劑</div> <div>　　2.稀釋劑為二甲苯，但是也可以用丙酮作為稀釋劑。稀釋比為1：1.5。但是也有資料說1：2甚至1：4的。</div> </div> <div class="page"> <p><a href="/index.php?m=cn&c=newsb&a=view&id=549" class="page">上一條：回收橡膠--橡膠種類代號</a></p> <p><a href="/index.php?m=cn&c=newsb&a=view&id=547" class="page">下一條：液體化工原料給我們帶來哪些危害</a></p>  <a href="/index.php?m=cn&c=newsb&a=index&tid=" title="返回列表" class="back">返回列表</a> </div> </div> </div> <div class="clear"></div> </div> </div>   <div class="icontact" > <div class="wl"> <div class="fri_link"> <p class="atitle"> <font>link</font> <span>友情鏈接</span> </p> <div class="nnf"> <a title="百度" target="_blank" style="background-image:url(/Upload/news/05A7BE923A31176C5B01704E244224EB.jpg);background-size:100px 50px;"></a> </div> </div> </div> </div> <div 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